The socialisation window is the period early in a puppy's life, roughly from around three to fourteen weeks old, when they're most open to new experiences shaping how they view the world long term. Positive exposure to new people, animals, sounds, surfaces, and situations during this window tends to build lasting confidence. The same is true in reverse, and a lack of exposure, or a frightening experience, during this period can have an outsized effect compared to the same experience later in life.
The exact age range varies slightly by breed and individual dog, but the general principle holds across most dogs: earlier experiences carry more long-term weight than the same experiences introduced later.